Free
surfaces in barrels or tanks allow air-oxygen to dissolve in wine at
rates thousands of times greater than the rate it diffuses through solids,
such as the barrel wall. Even with CO2 in the head-space, there is usually
still enough oxygen present, (CO2 dilutes air rather then displacing
it), to cause aldehydic wine near the surface and to enable aerobic
organisms to multiply on the surface, causing scum.
These
simple but patented flexible devices float on and in the wine to block
the free wine surface in tanks. Their use effectively converts a fixed-capacity
tank to a variable-capacity one, by greatly reducing the free wine surface-area
in contact with the ullaged head space, to less than when the tank is
full. This suppresses scum and bacteria formation to "safe"
levels, also greatly reducing the rate of development of volatle acidity.